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The paper aims to discuss the evaluation of anti-corrosive efficiency of conducting polymer, polypyrrole in water borne epoxy-polyamine coatings.

Polypyrrole (PPy) is synthesised by chemical oxidative polymerisation. The synthesised PPy is characterised by employing FT-IR, XRD, SEM and EDX analysis. The coatings are formulated using water borne epoxy cross-linked with aliphatic polyamine adduct and the effect of PPy on corrosion prevention is studied. PPy was used as anti-corrosive pigment in concentration varying from 1 to 5 wt.%. In addition to anti-corrosive property; mechanical properties, chemical resistance and weathering properties of the coatings containing PPy are studied, thereby obtaining a wholesome data about the quality and performance of these coatings.

The result obtained through various tests showed that the coating with 1 and 2% PPy exhibited excellent weathering resistance, mechanical properties and improved chemical resistance. Higher percentage loading of PPy (beyond 3 per cent) proves to be disastrous, as extended percolation networks are formed which results in rapid intense corrosion leading to fast coating breakdown.

The anti-corrosion property of the coating can be tested by means of atmospheric exposure such as Florida test which produces a real time evaluation of the anti-corrosive nature of the coating at natural condition rather than accelerated weathering, thereby providing more reliable performance data for intended application purpose.

The results find application in anti-corrosive/performance paints for industrial application.

This research paper presents the results of anti-corrosion behaviour of PPy in water borne epoxy-polyamide coating. Based on this result, a highly effective anti-corrosive coating can be formulated by the addition of small percentage of PPy in combination with other conventional pigments, thereby enhancing corrosion protection. But care must be taken so as to avoid formation of extended percolation network of PPy which leads to rapid coating breakdown.

Urethane Acrylate Oligomer with 100% solids was synthesised and characterised in order to study the application in electron beam curing with varying ratio of Trimethylol propane triacrylate (TMPTA). The purpose of this paper is to study effect of TMPTA addition on the crosslink density and different coating properties.

Polyester polyol was synthesised by reacting single diacid, adipic acid (AA), with Pentaerythritol (PENTA) and 1,6‐hexanediol (HD). Further, Urethane acrylate resin was synthesised by using Isophorone diisocyanate (IPDI), hydroxy ethyl acrylate (HEA) and Polyester polyol. The polyester polyol and urethane acrylate oligomer were characterised by 1H NMR, 13C NMR, FTIR and GPC. Further, TMPTA was added as a crosslinker to the urethane acrylate oligomer and cured by electron beam radiation. The cured UA films having varying concentration of TMPTA were employed to evaluate thermal property, contact angle analysis, mechanical and chemical properties.

The obtained results showed improvement in their chemical properties, mechanical properties, thermal properties and water contact angle at 20% of TMPTA iconcentration. The TMPTA also reduced the dose required for the curing.

The resin can be synthesised from different isocyanates as TDI, MDI and HMDI, etc. The study can also be done with different multi or mono functional monomers such as methacrylate, hexanediol diacrylate, ethylene glycol diacrylate, etc.

The paper provides the better solution to reduce the cost of the electron beam radiation required for the curing.

The method presented in the paper could be very useful for controlling environmental pollution; as the conventional method of curing releases volatile organic compounds (VOC).

In this paper, urethane acrylate and TMTPA cured with electron beam are shown to offer good coating properties. A high‐solid urethane acrylate coating would find numerous industrial applications in surface coatings.

The purpose of this paper is to quantify, evaluate and compare the implementation performance of a supplier development (SD) program using graph theoretic approach (GTA).

Broadly 13 critical success factors (CSFs) were identified and they were classified into four significant categories (SCs). Featuring these SCs and CSFs under each SC, GTA was proposed for evaluating the implementation performance of SD programs. The analysis was further extended to evaluate the performance of a SD program along the timeline to capture the other influences (if any), eventually compare the results with different performance situations and accordingly set the future targets.

In order to demonstrate the utility of the proposed approach it was applied to an Indian manufacturing company. The results obtained shown that there has been a significant growth achieved in the implementation performance of a SD program over a period of three years (i.e. 12 quarters) along the chosen SCs and CSFs under each SC. It was also found that still there was a performance gap and scope for improvement in the SD program of the case company.

The proposed approach is aimed at providing a procedure for evaluating the implementation performance of a SD program. This study is an attempt to assist a manufacturer to assess its SD program and accordingly define its course of actions.

Although many issues related to SD have been widely recognized and studied, there are no specific studies available in the literature to assess the implementation performance of SD programs along the timeline. The proposed model has the ability to capture the performance and interdependencies of SCs, CSFs under each SC and also to quantify the implementation performance of a SD program along the timeline.

The purpose of this paper is to quantify, evaluate and compare the environmental sustainability performance of supply chain for Indian steel industry using graph theoretic approach (GTA).

Broadly 12 environmental sustainability enablers (ESEs) were identified and they were classified into four significant categories (SCs). Featuring these SCs and ESEs under each SC, a methodology was proposed using GTA for evaluating the environmental sustainability performance of Indian steel companies. The analysis was further extended to compare the results with performance in different situations and accordingly set the future targets.

In order to demonstrate the utility of the proposed methodology, it was applied to an Indian steel company. The results obtained indicated that there have been significant growths achieved in the environmental sustainability performance over a period of five years. It was also found that a performance gap exists and it will reach the target value after two years.

The proposed approach is aimed at providing a procedure for evaluating the environmental sustainability performance. This study is an attempt to assist a steel industry to assess its sustainability program and accordingly define its course of actions.

Although many issues related to environmental sustainability have been widely recognized and studied, there are no specific studies available in the literature to assess the environmental sustainability performance along the timeline. The proposed model has the ability to capture the performance and interdependencies of SCs, ESEs under each SC and also to quantify the environmental sustainability performance along the timeline.